|
Records |
Links |
|
Author |
Smedley, P.L.; Kinniburgh, D.G. |
![find record details (via OpenURL) openurl](img/xref.gif)
|
|
Title |
Uranium in natural waters and the environment: Distribution, speciation and impact |
Type |
Journal Article |
|
Year |
2023 |
Publication |
Applied Geochemistry |
Abbreviated Journal |
|
|
|
Volume |
148 |
Issue |
|
Pages |
105534 |
|
|
Keywords |
Drinking water, Mine water, NORM, Radionuclide, Redox, U isotopes, Uranium, Uranyl |
|
|
Abstract ![sorted by Abstract field, ascending order (up)](img/sort_asc.gif) |
The concentrations of U in natural waters are usually low, being typically less than 4 μg/L in river water, around 3.3 μg/L in open seawater, and usually less than 5 μg/L in groundwater. Higher concentrations can occur in both surface water and groundwater and the range spans some six orders of magnitude, with extremes in the mg/L range. However, such extremes in surface water are rare and linked to localized mineralization or evaporation in alkaline lakes. High concentrations in groundwater, substantially above the WHO provisional guideline value for U in drinking water of 30 μg/L, are associated most strongly with (i) granitic and felsic volcanic aquifers, (ii) continental sandstone aquifers especially in alluvial plains and (iii) areas of U mineralization. High-U groundwater provinces are more common in arid and semi-arid terrains where evaporation is an additional factor involved in concentrating U and other solutes. Examples of granitic and felsic volcanic terrains with documented high U concentrations include several parts of peninsular India, eastern USA, Canada, South Korea, southern Finland, Norway, Switzerland and Burundi. Examples of continental sandstone aquifers include the alluvial plains of the Indo-Gangetic Basin of India and Pakistan, the Central Valley, High Plains, Carson Desert, Española Basin and Edwards-Trinity aquifers of the USA, Datong Basin, China, parts of Iraq and the loess of the Chaco-Pampean Plain, Argentina. Many of these plains host eroded deposits of granitic and felsic volcanic precursors which likely act as primary sources of U. Numerous examples exist of groundwater impacted by U mineralization, often accompanied by mining, including locations in USA, Australia, Brazil, Canada, Portugal, China, Egypt and Germany. These may host high to extreme concentrations of U but are typically of localized extent. The overarching mechanisms of U mobilization in water are now well-established and depend broadly on redox conditions, pH and solute chemistry, which are shaped by the geological conditions outlined above. Uranium is recognized to be mobile in its oxic, U(VI) state, at neutral to alkaline pH (7–9) and is aided by the formation of stable U–CO3(±Ca, Mg) complexes. In such oxic and alkaline conditions, U commonly covaries with other similarly controlled anions and oxyanions such as F, As, V and Mo. Uranium is also mobile at acidic pH (2–4), principally as the uranyl cation UO22+. Mobility in U mineralized areas may therefore occur in neutral to alkaline conditions or in conditions with acid drainage, depending on the local occurrence and capacity for pH buffering by carbonate minerals. In groundwater, mobilization has also been observed in mildly (Mn-) reducing conditions. Uranium is immobile in more strongly (Fe-, SO4-) reducing conditions as it is reduced to U(IV) and is either precipitated as a crystalline or ‘non-crystalline’ form of UO2 or is sorbed to mineral surfaces. A more detailed understanding of U chemistry in the natural environment is challenging because of the large number of complexes formed, the strong binding to oxides and humic substances and their interactions, including ternary oxide-humic-U interactions. Improved quantification of these interactions will require updating of the commonly-used speciation software and databases to include the most recent developments in surface complexation models. Also, given their important role in maintaining low U concentrations in many natural waters, the nature and solubility of the amorphous or non-crystalline forms of UO2 that result from microbial reduction of U(VI) need improved quantification. Even where high-U groundwater exists, percentage exceedances of the WHO guideline value are variable and often small. More rigorous testing programmes to establish usable sources are therefore warranted in such vulnerable aquifers. As drinking-water regulation for U is a relatively recent introduction in many countries (e.g. the European Union), testing is not yet routine or established and data are still relatively limited. Acquisition of more data will establish whether analogous aquifers elsewhere in the world have similar patterns of aqueous U distribution. In the high-U groundwater regions that have been recognized so far, the general absence of evidence for clinical health symptoms is a positive finding and tempers the scale of public health concern, though it also highlights a need for continued investigation. |
|
|
Address |
|
|
|
Corporate Author |
|
Thesis |
|
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
|
Language |
|
Summary Language |
|
Original Title |
|
|
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0883-2927 |
ISBN |
|
Medium |
|
|
|
Area |
|
Expedition |
|
Conference |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
THL @ christoph.kuells @ smedley_uranium_2023 |
Serial |
118 |
|
Permanent link to this record |
|
|
|
|
Author |
Aderemi, B.A.; Olwal, T.O.; Ndambuki, J.M.; Rwanga, S.S. |
![find record details (via OpenURL) openurl](img/xref.gif)
|
|
Title |
Groundwater levels forecasting using machine learning models: A case study of the groundwater region 10 at Karst Belt, South Africa |
Type |
Journal Article |
|
Year |
2023 |
Publication |
Systems and Soft Computing |
Abbreviated Journal |
|
|
|
Volume |
5 |
Issue |
|
Pages |
200049 |
|
|
Keywords |
Artificial intelligence, Forecasting model, Groundwater levels, Machine learning, Neural networks, Rainfall, Regression, Temperature, Time series |
|
|
Abstract ![sorted by Abstract field, ascending order (up)](img/sort_asc.gif) |
The crucial role which groundwater resource plays in our environment and the overall well-being of all living things can not be underestimated. Nonetheless, mismanagement of resources, over-exploitation, inadequate supply of surface water and pollution have led to severe drought and an overall drop in groundwater resources’ levels over the past decades. To address this, a groundwater flow model and several mathematical data-driven models have been developed for forecasting groundwater levels. However, there is a problem of unavailability and scarcity of the on-site input data needed by the data-driven models to forecast the groundwater level. Furthermore, as a result of the dynamics and stochastic characteristics of groundwater, there is a need for an appropriate, accurate and reliable forecasting model to solve these challenges. Over the years, the broad application of Machine Learning (ML) and Artificial Intelligence (AI) models are gaining attraction as an alternative solution for forecasting groundwater levels. Against this background, this article provides an overview of forecasting methods for predicting groundwater levels. Also, this article uses ML models such as Regressions Models, Deep Auto-Regressive models, and Nonlinear Autoregressive Neural Networks with External Input (NARX) to forecast groundwater levels using the groundwater region 10 at Karst belt in South Africa as a case study. This was done using Python Mx. Version 1.9.1., and MATLAB R2022a machine learning toolboxes. Moreover, the Coefficient of Determination (R2);, Root Mean Square Error (RMSE), Mutual Information gain, Mean Absolute Percentage Error (MAPE), Mean Squared Error (MSE), Mean Absolute Error (MAE), and the Mean Absolute Scaled Error (MASE)) models were the forecasting statistical performance metrics used to assess the predictive performance of these models. The results obtained showed that NARX and Support Vector Machine (SVM) have higher performance metrics and accuracy compared to other models used in this study. |
|
|
Address |
|
|
|
Corporate Author |
|
Thesis |
|
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
|
Language |
|
Summary Language |
|
Original Title |
|
|
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
2772-9419 |
ISBN |
|
Medium |
|
|
|
Area |
|
Expedition |
|
Conference |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
THL @ christoph.kuells @ Aderemi2023200049 |
Serial |
219 |
|
Permanent link to this record |
|
|
|
|
Author |
Kamruzzaman, M.; Chowdhury, A. |
![find record details (via OpenURL) openurl](img/xref.gif)
|
|
Title |
Flash flooding considerations aside: Knowledge brokering by the extension and advisory services to adapt a farming system to flash flooding |
Type |
Journal Article |
|
Year |
2023 |
Publication |
Heliyon |
Abbreviated Journal |
|
|
|
Volume |
9 |
Issue |
9 |
Pages |
19662 |
|
|
Keywords |
Flash flooding, Knowledge brokering, Extension and advisory services, Farming system, Climate change |
|
|
Abstract ![sorted by Abstract field, ascending order (up)](img/sort_asc.gif) |
The development of agriculture sector and livelihood in Bangladesh are threatened by various climatic stressors, including flash flooding. Therefore, Extension and advisory services (EAS) need to navigate the knowledge landscape effectively to connect various farm actors and help secure the optimum benefits of knowledge and information for making rational decisions. However, little is known how EAS can perform this task to combat various effects of climate change. This study investigates the means of brokering knowledge by the EAS to help the farming sector adapt to flash flooding. The research was conducted in the north-eastern part of Bangladesh with 73 staff of the Department of Agricultural Extension (DAE), the largest public EAS in Bangladesh. The results showed that DAE primarily dealt with crop production-related information. However, EAS did not navigate knowledge and information about flash flooding, such as weather forecasting and crop-saving-embankments updates, among the farming actors. Moreover, they missed the broad utilization of internet-based-communication channels to rapidly navigate information and knowledge about possible flash flooding and its adaptation strategies. This article provides some policy implications to effectively support the adaptation of farming system to flash flooding through EAS. |
|
|
Address |
|
|
|
Corporate Author |
|
Thesis |
|
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
|
Language |
|
Summary Language |
|
Original Title |
|
|
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
2405-8440 |
ISBN |
|
Medium |
|
|
|
Area |
|
Expedition |
|
Conference |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
THL @ christoph.kuells @ KAMRUZZAMAN2023e19662 |
Serial |
235 |
|
Permanent link to this record |
|
|
|
|
Author |
Holmes, M.; Campbell, E.E.; Wit, M. de; Taylor, J.C. |
![find record details (via OpenURL) openurl](img/xref.gif)
|
|
Title |
Can diatoms be used as a biomonitoring tool for surface and groundwater?: Towards a baseline for Karoo water |
Type |
Journal Article |
|
Year |
2023 |
Publication |
South African Journal of Botany |
Abbreviated Journal |
|
|
|
Volume |
161 |
Issue |
|
Pages |
211-221 |
|
|
Keywords |
Bioindicator, Diatom, Hydraulic fracturing, Karoo, Water quality |
|
|
Abstract ![sorted by Abstract field, ascending order (up)](img/sort_asc.gif) |
The environmental risks from shale gas extraction through the unconventional method of ‘fracking’ are considerable and impact on water supplies below and above ground. Since 2010 the recovery of natural shale gas through fracking has been proposed in parts of the fragile semi-arid ecosystems that make up the Karoo biome in South Africa. These unique ecosystems are heavily reliant on underground water, intermittent and ephemeral springs, which are at great risk of contamination by fracking processes. Diatoms are present in all water bodies and reflect aspects of the environment in which they are located. As the possibility of fracking has not been removed, the aim of the project was to determine if diatoms could be used for rapid biomonitoring of underground and surface waters in the Karoo. Over a period of 24 months, water samples and diatom species were collected simultaneously from 65 sites. A total of 388 diatom taxa were identified from 290 samples with seasonal and substrate variation affecting species composition but not the environmental information. Species diversity information, on the other hand, often varied significantly between substrates within a single sample. Analysis using CCA established that the diatom composition was affected by lithium, oxidized nitrogen, electrical conductivity, and sulphate levels in the sampled water. We conclude that changes in diatom community composition in the Karoo do reflect the water chemistry and could be useful as bioindicators. |
|
|
Address |
|
|
|
Corporate Author |
|
Thesis |
|
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
|
Language |
|
Summary Language |
|
Original Title |
|
|
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0254-6299 |
ISBN |
|
Medium |
|
|
|
Area |
|
Expedition |
|
Conference |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
THL @ christoph.kuells @ holmes_can_2023 |
Serial |
163 |
|
Permanent link to this record |
|
|
|
|
Author |
Wang, B.; Luo, Y.; Qian, J.-zhong; Liu, J.-hui; Li, X.; Zhang, Y.-hong; Chen, Q.-qian; Li, L.-yao; Liang, D.-ye; Huang, J. |
![find record details (via OpenURL) openurl](img/xref.gif)
|
|
Title |
Machine learning–based optimal design of the in-situ leaching process parameter (ISLPP) for the acid in-situ leaching of uranium |
Type |
Journal Article |
|
Year |
2023 |
Publication |
Journal of Hydrology |
Abbreviated Journal |
|
|
|
Volume |
626 |
Issue |
|
Pages |
130234 |
|
|
Keywords |
In-situ leaching, Injection rate design, Lixiviant concentration design, Machine learning, Simulation-optimisation, Uncertainty |
|
|
Abstract ![sorted by Abstract field, ascending order (up)](img/sort_asc.gif) |
The migration process of leached uranium in the in-situ leaching of uranium is considered a typical reactive transport problem. During this process, the lixiviant concentration and injection rate are important in-situ leaching process parameters (ISLPP) to efficiently recover uranium. However, several uncertain factors affect the outcomes of the ISLPP design. In addition, the repeated use of the reactive transport model (RTM) for investigating the acid in-situ leaching of uranium with the application of the Monte Carlo method leads to a substantial computational load. For this reason, a machine learning (ML)–based surrogate model was developed with the backpropagation neural network (BPNN) method to replace the RTM under the condition of uncertain parameters. Moreover, the simulated annealing optimisation model for ISLPP was created based on the proposed surrogate model. The optimal ISLPP was achieved that generated maximum profits from uranium recovery under different lixiviant prices, uranium prices and exploitation times. The optimal design framework of ISLPP based on the proposed ML algorithm was then applied in the Bayan-Uul sandstone-type uranium deposit in Inner Mongolia, China. From our analysis, it was demonstrated that the ML-based surrogate model exhibited great fitness with the RTM. The optimal results of the ISLPP indicated that the lixiviant concentration and injection rate could be adjusted based on the fluctuations in lixiviant price, uranium price and exploitation time. If the prices of sulphuric acid were high, a specific concentration of hydrogen peroxide could be injected into the injection well to promote the oxidation and dissolution of the uranium ore to increase the income from the uranium recovery. The optimisation model can also use the ISLPP scheme to boost the revenues from different lixiviant prices, uranium prices and exploitation times under the uncertainty of porosity, illustrating the applicability of the ML-based optimal design method of ISLPP in ISL mining. A general framework for developing surrogate models, as well as for conducting uncertainty analyses for a wide range of groundwater models was proposed here yielding valuable insights. |
|
|
Address |
|
|
|
Corporate Author |
|
Thesis |
|
|
|
Publisher |
|
Place of Publication |
|
Editor |
|
|
|
Language |
|
Summary Language |
|
Original Title |
|
|
|
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
|
Series Volume |
|
Series Issue |
|
Edition |
|
|
|
ISSN |
0022-1694 |
ISBN |
|
Medium |
|
|
|
Area |
|
Expedition |
|
Conference |
|
|
|
Notes |
|
Approved |
no |
|
|
Call Number |
THL @ christoph.kuells @ wang_machine_2023 |
Serial |
210 |
|
Permanent link to this record |