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Liu, Z., Tan, K., Li, C., Li, Y., Zhang, C., Song, J., et al. (2023). Geochemical and S isotopic studies of pollutant evolution in groundwater after acid in situ leaching in a uranium mine area in Xinjiang. Nuclear Engineering and Technology, 55(4), 1476–1484.
Abstract: Laboratory experiments and point monitoring of reservoir sediments have proven that stable sulfate reduction (SSR) can lower the concentrations of toxic metals and sulfate in acidic groundwater for a long time. Here, we hypothesize that SSR occurred during in situ leaching after uranium mining, which can impact the fate of acid groundwater in an entire region. To test this, we applied a sulfur isotope fractionation method to analyze the mechanism for natural attenuation of contaminated groundwater produced by acid in situ leaching of uranium (Xinjiang, China). The results showed that δ34S increased over time after the cessation of uranium mining, and natural attenuation caused considerable, area-scale immobilization of sulfur corresponding to retention levels of 5.3%–48.3% while simultaneously decreasing the concentration of uranium. Isotopic evidence for SSR in the area, together with evidence for changes of pollutant concentrations, suggest that area-scale SSR is most likely also important at other acid mining sites for uranium, where retention of acid groundwater may be strengthened through natural attenuation. To recapitulate, the sulfur isotope fractionation method constitutes a relatively accurate tool for quantification of spatiotemporal trends for groundwater during migration and transformation resulting from acid in situ leaching of uranium in northern China.
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Kurmanseiit, M. B., Tungatarova, M. S., Royer, J. - J., Aizhulov, D. Y., Shayakhmetov, N. M., & Kaltayev, A. (2023). Streamline-based reactive transport modeling of uranium mining during in-situ leaching: Advantages and drawbacks. Hydrometallurgy, 220, 106107.
Abstract: Reactive transport modeling is known to be computationally intensive when applied to 3D problems. Transforming sequential computing on the computer processor units (CPU) into parallelized computation on the high-performance parallel graphic processor units (GPU) is a classical approach to increasing computational performance. Another complementary approach is to decompose a complex 3D modeling problem into a set of simpler 1D problems using streamline approaches which can be easily parallelized, therefore reducing computation time. This paper investigates solutions to the equations governing dissolution and transport using streamlines coupled with a parallelization approach. In addition, an analytical solution to the dissolution and transfer equations of uranium describing the In-Situ Leaching (ISL) mining recovery is found using an approximation series to the 2nd order. The analytical solution is compared to the 1D numerical resolution along the streamlines and to the 3D simulation results superimposed on the streamline. Both approaches give similar results with a relative error of \textless2 % (2%). The proposed methodology is then applied to a case study in which the classical 3D resolution is compared to the newly suggested streamline solution, demonstrating that the streamline approach increases computational performances by a factor ranging from hundred to thousand depending on the complexity of the grid-block model.
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Milena-Pérez, A., Piñero-García, F., Benavente, J., Expósito-Suárez, V. M., Vacas-Arquero, P., & Ferro-García, M. A. (2021). Uranium content and uranium isotopic disequilibria as a tool to identify hydrogeochemical processes. Journal of Environmental Radioactivity, 227, 106503.
Abstract: This paper studies the uranium content and uranium isotopic disequilibria as a tool to identify hydrogeochemical processes from 52 groundwater samples in the province of Granada (Betic Cordillera, southeastern Spain). According to the geological complexity of the zone, three groups of samples have been considered. In Group 1 (thermal waters; longest residence time), the average uranium content was 2.63 ± 0.16 μg/L, and 234U/238U activity ratios (AR) were the highest of all samples, averaging 1.92 ± 0.30. In Group 2 (mainly springs from carbonate aquifers; intermediate residence time), dissolved uranium presented an average value of 1.34 ± 0.13 μg/L, while AR average value was 1.38 ± 0.25. Group 3 comes from pumping wells in a highly anthropized alluvial aquifer. In this group, where the residence time of the groundwater is the shortest of the three, average uranium content was 5.28 ± 0.26 μg/L, and average AR is the lowest (1.17 ± 0.12). In addition, the high dissolved uranium value and the low AR brought to light the contribution of fertilizers (Group 3). In the three groups, 235U/238U activity ratios were similar to the natural value of 0.046. Therefore, 235U detected in the samples comes from natural sources. This study is completed with the determination of major ions and physicochemical parameters in the groundwater samples and the statistical analysis of the data by using the Principal Component Analysis. This calculation indicates the correlation between uranium isotopes and bicarbonate and nitrate anions.
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Belz, L., Schüller, I., Wehrmann, A., Köster, J., & Wilkes, H. (2020). The leaf wax biomarker record of a Namibian salt pan reveals enhanced summer rainfall during the Last Glacial-Interglacial Transition. Palaeogeography, Palaeoclimatology, Palaeoecology, 543, 109561.
Abstract: Conventional continental geoarchives are rarely available in arid southern Africa. Therefore, palaeoclimate data in this area are still patchy and late Quaternary climate development is only poorly understood. In the western Kalahari, salt pans (playas, ephemeral lakes) are common and can feature quasi-continuous sedimentation. This study presents the first climate-related biomarker record using sediments from the Omongwa Pan, a Kalahari salt pan located in eastern Namibia. Our approach to reconstruct vegetation and hydrology focuses on biogeochemical bulk parameters and plant wax-derived lipid biomarkers (n-alkanes, n-alkanols, and fatty acids) and their compound-specific carbon and hydrogen isotopic compositions. The presented record reaches back to 27 ka. During the glacial, rather low δ2H values of n-alkanes and low sediment input exclude a strong influence of winter rainfall. n-Alkane and n-alkanol distributions and δ13C values of n-hentriacontane (n-C31) indicate a shift to a vegetation with a higher proportion of C4 plants at the end of the Last Glacial Maximum until the end of Heinrich Stadial I (ca. 18–14.8 ka), which we interpret to indicate an abrupt excursion to a short wetter period likely to be caused by a temporary southward shift of the Intertropical Convergence Zone. Shifts in δ2H values of n-C31 and plant wax parameters give evidence for changes to drier conditions during early Holocene. Comparison of this dataset with representative continental records from the region points to a major influence of summer rainfall at Omongwa Pan during the regarded time span and demonstrates the potential of southern African salt pans as archives for biomarker-based climate proxies.
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Doulgeris, C., Tziritis, E., Pisinaras, V., Panagopoulos, A., & Külls, C. (2020). Prediction of seawater intrusion to coastal aquifers based on non-dimensional diagrams. In EGU Geophysical Abstracts (4073).
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Leibundgut, C., Maloszewski, P., & Külls, C. (2009). Tracers in Hydrology. John Wiley & Sons, Ltd.
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Külls, C. (2001). Groundwater of the North-Western Kalahari, Namibia: estimation of recharge and quantification of the flow system. Doctoral thesis, Hydrogeologie und Umwelt, .
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Döll, P., Krol, M., Fuhr, D., Gaiser, T., Herfort, J., Höynck, S., et al. (2003). Integrated scenarios of regional development in Ceará and Piauí. In Global Change and Regional Impacts (pp. 19–41). Springer, Berlin, Heidelberg.
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Voerkelius, S., Külls, C., Santiago, M. M. F., Frischkorn, H., dos Santos Semrau, L. A., Heinrichs, G., et al. (2003). Investigations on water management and water quality in Picos/PI and Tauá/CE. In Global change and regional impacts (pp. 173–184). Springer, Berlin, Heidelberg.
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Külls, C., Leibundgut, C., Schwarz, U., & Schick, A. P. (1995). Channel infiltration study using dye tracers. IAHS Publications-Series of Proceedings and Reports-Intern Assoc Hydrological Sciences, 232, 429–436.
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