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Magaritz, M.; Nadler, A.; Kafri, U.; Arad, A. |
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Title |
Hydrogeochemistry of continental brackish waters in the southern Coastal Plain, Israel |
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Journal Article |
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Year |
1984 |
Publication |
Chemical Geology |
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42 |
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1 |
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159-176 |
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Abstract  |
The southern Coastal Plain in Israel incorportates a transitional fringe of the desert in which three different chemical types of groundwater are found: (1) near-surface waters from springs along the Besor River course: (2) shallow- to moderate-depth waters from the slightly westward-dipping Pleistocene coastal aquifer (this aquifer, which consists of sandstone layers of the Kurkar Group, is recharged in the Coastal Plain); and (3) deep waters of the westward-dipping Upper Cretaceous Judea Group carbonates, which are recharged in the mountains in the east. A thick aquiclude of Upper Cretaceous-Tertiary rocks separates the Judea Group aquifer from the overlying coastal aquifer in the southern Coastal Plain. Isotopically light oxygen and depleted deuterium characterize the Judea Group waters, as expected from high-altitude recharge. The isotopic composition of the Coastal Plain waters is variable, but for the most part enriched in 18O and D. Within the southern Coastal Plain aquifer a southern subgroup comprises waters more depleted in heavy isotopes than those of either the northern or eastern subgroups. The Besor waters are isotopically similar to the Judea Group waters, reflecting their origin in the mountain region, and flow through the surficial river gravels and sands. It is suggested that leakage of the Besor waters into the underlying southern Coastal Plain aquifer results in mixing of the two water types. The most prominent chemical feature characterizing the groundwater of the southern Coastal Plain is Na+Cl− \textgreater 1. This Na+Cl− ratio can be maintained only by a continuous input from a non-marine source of Na. The most plausible source of this Na is the dissolution of feldspar derived from the windblown loess deposits which cover the area and/or leaching of trona minerals found in the unsaturated zone, combined with base-exchange processes. |
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0009-2541 |
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THL @ christoph.kuells @ Magaritz1984 |
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31 |
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Llopis-Albert, C.; Merigó, J.M.; Xu, Y. |
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Title |
A coupled stochastic inverse/sharp interface seawater intrusion approach for coastal aquifers under groundwater parameter uncertainty |
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Journal Article |
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Year |
2016 |
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Journal of Hydrology |
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540 |
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774-783 |
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This paper presents an alternative approach to deal with seawater intrusion problems, that overcomes some of the limitations of previous works, by coupling the well-known SWI2 package for MODFLOW with a stochastic inverse model named GC method. On the one hand, the SWI2 allows a vertically integrated variable-density groundwater flow and seawater intrusion in coastal multi-aquifer systems, and a reduction in number of required model cells and the elimination of the need to solve the advective-dispersive transport equation, which leads to substantial model run-time savings. On the other hand, the GC method allows dealing with groundwater parameter uncertainty by constraining stochastic simulations to flow and mass transport data (i.e., hydraulic conductivity, freshwater heads, saltwater concentrations and travel times) and also to secondary information obtained from expert judgment or geophysical surveys, thus reducing uncertainty and increasing reliability in meeting the environmental standards. The methodology has been successfully applied to a transient movement of the freshwater-seawater interface in response to changing freshwater inflow in a two-aquifer coastal aquifer system, where an uncertainty assessment has been carried out by means of Monte Carlo simulation techniques. The approach also allows partially overcoming the neglected diffusion and dispersion processes after the conditioning process since the uncertainty is reduced and results are closer to available data. |
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0022-1694 |
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THL @ christoph.kuells @ Llopis-Albert2016 |
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30 |
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Mongelli, G.; Monni, S.; Oggiano, G.; Paternoster, M.; Sinisi, R. |
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Tracing groundwater salinization processes in coastal aquifers: a hydrogeochemical and isotopic approach in the Na-Cl brackish waters of northwestern Sardinia, Italy |
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2013 |
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Hydrology and Earth System Sciences |
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17 |
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7 |
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2917-2928 |
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salinization, isotopes, Sardinia |
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Throughout the Mediterranean, salinization threatens water quality, especially in coastal areas. This salinization is the result of concomitant processes related to both seawater intrusion and water–rock interaction, which in some cases are virtually indistinguishable. In the Nurra region of northwestern Sardinia, recent salinization related to marine water intrusion has been caused by aquifer exploitation. However, the geology of this region records a long history from the Palaeozoic to the Quaternary, and is structurally complex and comprises a wide variety of lithologies, including Triassic evaporites. Determining the origin of the saline component of the Jurassic and Triassic aquifers in the Nurra region may provide a useful and more general model for salinization processes in the Mediterranean area, where the occurrence of evaporitic rocks in coastal aquifers is a common feature. In addition, due to intensive human activity and recent climatic change, the Nurra has become vulnerable to desertification and, in common with other Mediterranean islands, surface water resources periodically suffer from severe shortages. With this in mind, we report new data regarding brackish and surface waters (outcrop and lake samples) of the Na-Cl type from the Nurra region, including major ions and selected trace elements (B, Br, I, and Sr), in addition to isotopic data including δ18O, δD in water, and δ34S and δ18O in dissolved SO4. To identify the origin of the salinity more precisely, we also analysed the mineralogical and isotopic composition of Triassic evaporites. The brackish waters have Cl contents of up to 2025 mg L−1 , and the ratios between dissolved ions and Cl, with the exception of the Br / Cl ratio, are not those expected on the basis of simple mixing between rainwater and seawater. The δ18O and δD data indicate that most of the waters fall between the regional meteoric water line and the global meteoric water line, supporting the conclusion that they are meteoric in origin. A significant consequence of the meteoric origin of the Na-Cl-type water studied here is that the Br / Cl ratio, extensively used to assess the origin of salinity in fresh water, should be used with care in carbonate aquifers that are near the coast. Overall, δ34S and δ18O levels in dissolved SO4 suggest that water–rock interaction is responsible for the Na-Cl brackish composition of the water hosted by the Jurassic and Triassic aquifers of the Nurra, and this is consistent with the geology and lithological features of the study area. Evaporite dissolution may also explain the high Cl content, as halite was detected within the gypsum deposits. Finally, these Na-Cl brackish waters are undersaturated with respect to the more soluble salts, implying that in a climate evolving toward semi-arid conditions, the salinization process could intensify dramatically in the near future. |
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Copernicus |
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THL @ christoph.kuells @ hess-17-2917-2013 |
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79 |
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Abstract |
Throughout the Mediterranean, salinization threatens water quality, especially in coastal areas. This salinization is the result of concomitant processes related to both seawater intrusion and water–rock interaction, which in some cases are virtually indistinguishable. In the Nurra region of northwestern Sardinia, recent salinization related to marine water intrusion has been caused by aquifer exploitation. However, the geology of this region records a long history from the Palaeozoic to the Quaternary, and is structurally complex and comprises a wide variety of lithologies, including Triassic evaporites. Determining the origin of the saline component of the Jurassic and Triassic aquifers in the Nurra region may provide a useful and more general model for salinization processes in the Mediterranean area, where the occurrence of evaporitic rocks in coastal aquifers is a common feature. In addition, due to intensive human activity and recent climatic change, the Nurra has become vulnerable to desertification and, in common with other Mediterranean islands, surface water resources periodically suffer from severe shortages. With this in mind, we report new data regarding brackish and surface waters (outcrop and lake samples) of the Na-Cl type from the Nurra region, including major ions and selected trace elements (B, Br, I, and Sr), in addition to isotopic data including δ18O, δD in water, and δ34S and δ18O in dissolved SO4. To identify the origin of the salinity more precisely, we also analysed the mineralogical and isotopic composition of Triassic evaporites. The brackish waters have Cl contents of up to 2025 mg L−1 , and the ratios between dissolved ions and Cl, with the exception of the Br / Cl ratio, are not those expected on the basis of simple mixing between rainwater and seawater. The δ18O and δD data indicate that most of the waters fall between the regional meteoric water line and the global meteoric water line, supporting the conclusion that they are meteoric in origin. A significant consequence of the meteoric origin of the Na-Cl-type water studied here is that the Br / Cl ratio, extensively used to assess the origin of salinity in fresh water, should be used with care in carbonate aquifers that are near the coast. Overall, δ34S and δ18O levels in dissolved SO4 suggest that water–rock interaction is responsible for the Na-Cl brackish composition of the water hosted by the Jurassic and Triassic aquifers of the Nurra, and this is consistent with the geology and lithological features of the study area. Evaporite dissolution may also explain the high Cl content, as halite was detected within the gypsum deposits. Finally, these Na-Cl brackish waters are undersaturated with respect to the more soluble salts, implying that in a climate evolving toward semi-arid conditions, the salinization process could intensify dramatically in the near future. |
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THL @ christoph.kuells @ |
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80 |
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Liu, F.; Wang, S.; Wang, L.; Shi, L.; Song, X.; Yeh, T.-C.J.; Zhen, P. |
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Title |
Coupling hydrochemistry and stable isotopes to identify the major factors affecting groundwater geochemical evolution in the Heilongdong Spring Basin, North China |
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Journal Article |
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2019 |
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Journal of Geochemical Exploration |
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205 |
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Understanding the interference of natural processes and anthropogenic activities in geochemical evolution of groundwater is vital for groundwater sustainable management in water-stressed regions. This study is devoted to the identification of the main factors controlling the evolution of groundwater chemistry by the combined use of hydrogeochemical indicators along with isotope tracers in the Heilongdong Spring Basin, North China. Thirty-nine groundwater samples and twelve surface water samples were collected, and major ions and stable isotopes were measured during the two campaigns (December 2017 and August 2018). The isotope approach indicates that the groundwater is recharged by precipitation infiltration after evaporation, and interacts with surface water along preferential flow paths in fault zones and karst conduits. Currently, the main chemical facies of groundwater evolve from Ca-HCO3 and Ca-Mg-HCO3 types with low TDS, through Ca-Mg-HCO3-SO4 and Ca-HCO3-SO4 types with moderate TDS, to Ca-SO4, Ca-SO4-Cl and CaCl types with high TDS. Apart from natural processes (involving dissolution/precipitation of minerals, cation exchange, and evaporation) regulating the groundwater quality, the stagnant zones also play a crucial role in the formation of severe localized nitrate contamination. The deterioration in groundwater quality can be attributed to anthropogenic factors (including the change in groundwater exploitation, the leaching of solid waste, and the overuse of agricultural fertilizers). The high loads of agricultural fertilizers in irrigation return flows are likely to be the main contributor of the dissolved nitrate in groundwater. The findings of this work not only have important implications for groundwater sustainable utilization, but also could serve as a template for other rapidly industrialized and water-stressed regions. |
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English |
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0375-6742 |
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THL @ christoph.kuells @ Liu2019 |
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29 |
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