Abstract: Groundwater is an important water resource for agricultural irrigation and urban and industrial utilization in the coastal regions of northern China. In the past 5 decades, coastal groundwater salinization in the Yang–Dai river plain has become increasingly serious under the influence of anthropogenic activities and climatic change. It is pivotal for the scientific management of coastal water resources to accurately understand groundwater salinization processes and their causative factors. Hydrochemical (major ion and trace element) and stable isotopic (δ18O and δ2H) analysis of different water bodies (surface water, groundwater, geothermal water and seawater) were conducted to improve understanding of groundwater salinization processes in the plain's Quaternary aquifer. Saltwater intrusion due to intensive groundwater pumping is a major process, either by vertical infiltration along riverbeds which convey saline surface water inland, and/or direct subsurface lateral inflow. Trends in salinity with depth indicate that the former may be more important than previously assumed. The proportion of seawater in groundwater is estimated to have reached up to 13 % in shallow groundwater of a local well field. End-member mixing calculations also indicate that the geothermal water with high total dissolved solids (up to 10.6 g L−1) with depleted stable isotope compositions and elevated strontium concentrations (> 10 mg L−1) also mixes locally with water in the overlying Quaternary aquifers. This is particularly evident in samples with elevated Sr ∕ Cl ratios (> 0.005 mass ratio). Deterioration of groundwater quality by salinization is also clearly exacerbated by anthropogenic pollution. Nitrate contamination via intrusion of heavily polluted marine water is evident locally (e.g., in the Zaoyuan well field); however, more widespread nitrate contamination due to other local sources such as fertilizers and/or domestic wastewater is evident on the basis of NO3 ∕ Cl ratios. This study provides an example of how multiple geochemical indicators can delineate different salinization processes and guide future water management practices in a densely populated water-stressed coastal region.

Abstract: In arid and semi-arid areas, the groundwater is the main source of water supply and agricultural activity. Overexploitation of coastal aquifers and pollution vulnerability are among the main problems related to groundwater resources assessment and management in these zones. In fact, in the last decades, these resources have been threatened by a degradation of their quality and quantity that furthers natural and anthropic effects, such as climate change, seawater intrusion and overexploitation. However, the protection and management of these resources requires knowledge of the origin of their mineralization. In this study, the Essaouira basin is selected as a typical example. Stable isotopes (18O and 2H) together with geochemical data were used to identify the groundwater salinization origin in the coastal aquifers of the Essaouira basin. The results of both the approaches show that the groundwater mineralization is due to: (1) the dissolution of salt minerals, (2) the ion exchange phenomena, (3) seawater intrusion, and (4) sulphate reduction. Also, the recharge is supported by fast infiltration of oceanic precipitation without significant evaporation.

Abstract: It has been suggested in a number of historical notes that it was neither Willem Badon Ghijben nor Alexander Herzberg who formulated the famous principle now carrying their name, which relates the water-table elevation to the depth of the freshwater saltwater interface in coastal aquifers. In this paper, a systematic review of the literature pre-dating the publication of their work is presented. The aim is to establish to what extent these previous works captured the essence of the Ghijben-Herzberg principle, that is, the combination of a correct conceptual model of the hydrogeological conditions with a quantitative relationship. It was found that references to coastal fresh groundwater reserves can be traced back to Roman times, while the earliest detailed descriptions of a freshwater lens that could be found dates from the eighteenth century. The correct understanding of the hydrostatic equilibrium between fresh and salt groundwater is evident in works from the early nineteenth century. However, it was Badon Ghijben and Herzberg who combined this with the correct understanding of the groundwater conditions of a freshwater lens. It was further found that Herzberg had already recorded his findings in 1888 in a hand-written report, confirming speculation that such a report might exist.