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Pulido-Leboeuf, P.; Pulido-Bosch, A.; Calvache, M.L.; Vallejos, Á.; Andreu, J.M. |
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Strontium, SO42-/Cl- and Mg2+/Ca2+ ratios as tracers for the evolution of seawater into coastal aquifers: the example of Castell de Ferro aquifer (SE Spain) |
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2003 |
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Comptes Rendus Geoscience |
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335 |
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14 |
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1039-1048 |
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Elsevier |
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THL @ luqianxue.zhang @ pulido2003strontium |
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71 |
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Wigley, T.M.L.; Plummer, L.N. |
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Title |
Mixing of carbonate waters |
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Journal Article |
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Year |
1976 |
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Geochimica et Cosmochimica Acta |
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40 |
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9 |
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989-995 |
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When mineral solutions of different compositions are mixed, the molalities and activities of individual ions in the mixture are often non-linear functions of their end-member values. This non-linearity is particularly significant in determining mineral saturation levels. Mixtures of saturated solutions may be either undersaturated or supersaturated depending on the end-member compositions and the physical conditions in which end-members and their mixtures exist. In carbonate solutions important non-linear effects occur due to redistribution of carbonate species. In extreme cases this causes mixture pH to be below both the end-member pH values. A simple but precise computer program (WATMIX) has been developed for calculating mixture composition for closed and open system mixing of arbitrary end-members. A number of mixing examples are considered which allow one to isolate three important processes leading to non-linear behaviour: the algebraic effect, the δPCO2 effect, and the ionic strength effect. |
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0016-7037 |
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THL @ christoph.kuells @ Wigley1976 |
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40 |
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Nadler, A.; Magaritz, M.; Mazor, E. |
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Title |
Chemical reactions of sea water with rocks and freshwater: Experimental and field observations on brackish waters in Israel |
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1980 |
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Geochimica et Cosmochimica Acta |
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44 |
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6 |
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879-886 |
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Four major processes are observed to take place in the coastal aquifer of Israel, detectable even in the short times of water contact with the carbonate-containing host rocks. Three are chemical reactions, Ca2+-Mg2+ exchange, Na+-Ca2+ or Na+-Mg2+ base exchange, SO2−4 reduction and the fourth is dilution by freshwater. These reactions and their effects on the chemical composition of the waters were demonstrated experimentally. The range of chemical changes observed in the laboratory experiments overlap the range of the studied natural waters. This indicates that simulation of geologically long-term rock-water interaction could be achieved in laboratory experiments even at low temperatures. |
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0016-7037 |
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THL @ christoph.kuells @ Nadler1980 |
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33 |
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Qi, H.; Ma, C.; He, Z.; Hu, X.; Gao, L. |
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Title |
Lithium and its isotopes as tracers of groundwater salinization: A study in the southern coastal plain of Laizhou Bay, China |
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Journal Article |
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2019 |
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The Science of the Total Environment |
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Sci Total Environ |
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650 |
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Pt 1 |
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878-890 |
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Brine and seawater intrusion; Groundwater salinization; Hydrochemistry; Lithium isotope; Southern coastal plain of Laizhou Bay |
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In the southern coastal plain of Laizhou Bay, due to intensive exploitation of groundwater since the early 1970s, the shallow aquifer has been severely influenced by saltwater intrusion, which causes the extraction to shift from shallow to deeper aquifer changing the hydrogeological condition greatly. This study was conducted to investigate the groundwater salinization using hydrochemistry and H, O and Li isotope data. Dissolved Li shows a linear correlation with Cl and Br in seawater, brine and saline groundwater indicating the marine Li source, whereas the enrichment of Li in surface water, brackish and fresh groundwater is impacted by dissolution of silicate minerals. The analyses of hydrochemistry and isotopes (H, O and Li) indicate that brine originated from seawater evaporation, followed by mixing processes and some water-rock interactions; shallow saline groundwater originated from brine diluted with seawater and fresh groundwater; deep saline groundwater originated from seawater intrusion. The negative correlation of δ(7)Li and Li/Na in surface water, brackish and fresh groundwater is contrary to the general conclusion, indicating the slow weathering of silicate minerals and hydraulic interaction between surface water and shallow groundwater in this area. The analyses of hydrochemistry and isotopes (Li, H and O) can well identify the salinity sources and isotope fractionation in groundwater flow and mixing, especially groundwater with high TDS. As both mixing with saltwater and isotope fractionation can explain the combination of high δ(7)Li and low TDS in brackish groundwater, isotope fractionation may limit their use in recognizing salinity sources of groundwater with low TDS. |
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School of Environmental Studies, China University of Geosciences, Wuhan 430074, China |
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0048-9697 |
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PMID:30308862 |
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THL @ christoph.kuells @ |
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184 |
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Author |
Llopis-Albert, C.; Merigó, J.M.; Xu, Y. |
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Title |
A coupled stochastic inverse/sharp interface seawater intrusion approach for coastal aquifers under groundwater parameter uncertainty |
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2016 |
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Journal of Hydrology |
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540 |
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774-783 |
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This paper presents an alternative approach to deal with seawater intrusion problems, that overcomes some of the limitations of previous works, by coupling the well-known SWI2 package for MODFLOW with a stochastic inverse model named GC method. On the one hand, the SWI2 allows a vertically integrated variable-density groundwater flow and seawater intrusion in coastal multi-aquifer systems, and a reduction in number of required model cells and the elimination of the need to solve the advective-dispersive transport equation, which leads to substantial model run-time savings. On the other hand, the GC method allows dealing with groundwater parameter uncertainty by constraining stochastic simulations to flow and mass transport data (i.e., hydraulic conductivity, freshwater heads, saltwater concentrations and travel times) and also to secondary information obtained from expert judgment or geophysical surveys, thus reducing uncertainty and increasing reliability in meeting the environmental standards. The methodology has been successfully applied to a transient movement of the freshwater-seawater interface in response to changing freshwater inflow in a two-aquifer coastal aquifer system, where an uncertainty assessment has been carried out by means of Monte Carlo simulation techniques. The approach also allows partially overcoming the neglected diffusion and dispersion processes after the conditioning process since the uncertainty is reduced and results are closer to available data. |
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0022-1694 |
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THL @ christoph.kuells @ Llopis-Albert2016 |
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