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Author Moral, F.; Cruz-Sanjulián, J.J.; Olías, M. url  doi
openurl 
  Title Geochemical evolution of groundwater in the carbonate aquifers of Sierra de Segura (Betic Cordillera, southern Spain) Type Journal Article
  Year 2008 Publication Journal of Hydrology Abbreviated Journal  
  Volume 360 Issue 1 Pages 281-296  
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  Abstract Sierra de Segura (Betic Cordillera), with a total area of over 3000km2, is the source of the two principal rivers in southern Spain, the Guadalquivir and the Segura. Due to the orographic effect of these mountains, precipitations are considerably more abundant than in nearby lowland areas, where the climate is semi-arid. Sierra de Segura is constituted of Mesozoic and Cenozoic sedimentary rocks, among which there are thick limestone–dolomitic formations which have given rise to extensive outcrops of permeable materials. In geomorphological terms, there is a large plateau intensively karstified that constitutes the main recharge area. Discharge takes place via a large number of springs, of which the 50 most important add up to a mean spring flow of about 13,500l/s. The active geochemical processes in aquifers of Sierra de Segura, with their corresponding time sequence, are: dissolution of CO2, dissolution of calcite, incongruent dissolution of dolomite, dedolomitization, exsolution of CO2, and precipitation of calcite. More evolved water has higher temperature, magnesium content and Mg/Ca ratio; therefore, these parameters can be utilised as indicators of the degree of hydrochemical evolution. In addition, a good correlation between water temperature and magnesium concentration (or Mg/Ca ratio) indicates that an increase in temperature accelerates the kinetics of the dissolution of dolomite. Finally, the distribution of the temperatures in the vadose zone, determined by atmospheric thermal gradient, implies an apparent stratification of the predominant hydrochemical processes and of the groundwater physical and chemical characteristics.  
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  ISSN (down) 0022-1694 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Moral2008 Serial 32  
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Author Stigter, T.Y.; van Ooijen, S.P.J.; Post, V.E.A.; Appelo, C.A.J.; Carvalho Dill, A.M.M. doi  openurl
  Title A hydrogeological and hydrochemical explanation of the groundwater composition under irrigated land in a Mediterranean environment, Algarve, Portugal Type Journal Article
  Year 1998 Publication Journal of Hydrology Abbreviated Journal  
  Volume 208 Issue 3 Pages 262-279  
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  Abstract In the Campina de Faro, in the south of Portugal, agricultural practices have a large impact on groundwater composition. These practices involve pumping of water for irrigation from combinations of large diameter, shallow wells (noras) and small diameter, deep boreholes (furos). Excess irrigation water returns to the aquifer and mixes with water from the regional groundwater flow system. This irrigation return flow is concentrated by strong evapotranspiration and by flushing of fertilisers. The concentration increase induces cation exchange, whereby Ca on the soil exchanger is replaced by Na. The mixing in the aquifer allows application of a mixing cell model which may then be used to calculate transmissivities from the Cl mass balance. The calculations are complicated by the time-variant behaviour of Cl and the method is adjusted to calculate the change of chloride in time. Results from the calculations appear to be in good agreement with hydrochemical observations.  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Stigter1998 Serial 38  
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Author Vengosh, A.; Rosenthal, E. doi  openurl
  Title Saline groundwater in Israel: its bearing on the water crisis in the country Type Journal Article
  Year 1994 Publication Journal of Hydrology Abbreviated Journal  
  Volume 156 Issue 1 Pages 389-430  
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  Abstract One of the major causes for the deterioration of water quality bearing heavily on the water crisis in Israel is the ongoing contamination of its water resources by saline water bodies. The present paper reviews the geochemical processes forming saline water, lists and explains certain chemical and isotopic parameters which enable understanding these processes and describes the saline groundwater bodies and various salinization phenomena occurring in the country’s various aquifers. Deterioration of groundwater in Israel is caused by numerous natural processes such as encroachment of sea water, migration of connate, highly pressurized brines penetrating into fresh groundwater, by subsurface dissolution of soluble salts originating in surrounding country rocks and by water-rock interaction. In addition to sea water, two saline water bodies were identified as the main factors causing salinization of fresh groundwater: (a) Ca-chloride brines encountered in the Jordan-Dead Sea Rift Valley, in various parts of the Negev and of the Coastal Plain, and (b) Na-chloride saline water identified in the subsurface of the Negev and in the southern part of the Coastal Plain. Intensive exploitation of groundwater in Israel has disturbed the natural equilibrium which prevailed between fresh and saline water. The newly established groundwater flow regimes have facilitated the migration of saline water bodies, their participation in the active hydrological cycle and the progressive contamination of fresh groundwater. These processes which were not anticipated by planners and water resources managers emphasize that large-scale groundwater exploitation was undertaken without giving sufficient consideration to the occurrence and subsurface migration of saline water and brines.  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Vengosh1994 Serial 39  
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Author Zhou, X.; Li, C. url  openurl
  Title Hydrogeochemistry of deep formation brines in the central Sichuan Basin, China Type Journal Article
  Year 1992 Publication Journal of Hydrology Abbreviated Journal  
  Volume 138 Issue 1 Pages 1-15  
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  Abstract Subsurface brines are abundant in the Sichuan Basin, China. Five brine-bearing aquifers have been identified within rocks of Triassic age in the central part of the basin. These are of two types: brine-bearing clastic and brine-bearing carbonate aquifers. Brines in this region have high total dissolved solids and chemical species that are different from those of evaporatively concentrated seawater. Deep formation brines in clastic aquifers, in which evaporites do not exist, are characterized by high concentrations of Ca, Sr, Ba, Br and I, low concentrations of Mg and K, and lack of SO4, and are dominated by the NaCaCl type. Brines in carbonate aquifers, which have interbeds of evaporites, are characterized by high total dissolved solids, low concentrations of Ca, Mg and SO4, and lack of Ba, and are of the NaCl type. The brines in clastic aquifers originate from connate continental sedimentary waters mixed with marine waters; membrane filtration through shales has played an important part in modifying the chemical compositions and increasing the salinity of the brines. Those in carbonate aquifers are bittern marine sedimentary waters, with chemical compositions mainly controlled by precipitation of evaporites.  
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  Area Asia Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ Zhou19921 Serial 41  
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Author Ladouche, B.; Luc, A.; Nathalie, D. url  openurl
  Title Chemical and isotopic investigation of rainwater in Southern France (1996–2002): Potential use as input signal for karst functioning investigation Type Journal Article
  Year 2009 Publication Journal of Hydrology Abbreviated Journal  
  Volume 367 Issue 1-2 Pages 150-164  
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  Corporate Author Thesis  
  Publisher Elsevier Place of Publication Editor  
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  Notes Approved no  
  Call Number THL @ luqianxue.zhang @ Ladouche2009 Serial 58  
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