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Author Petelet-Giraud, E.; Négrel, P.; Aunay, B.; Ladouche, B.; Bailly-Comte, V.; Guerrot, C.; Flehoc, C.; Pezard, P.; Lofi, J.; Dörfliger, N.
Title Coastal groundwater salinization: Focus on the vertical variability in a multi-layered aquifer through a multi-isotope fingerprinting (Roussillon Basin, France) Type Journal Article
Year 2016 Publication Science of The Total Environment Abbreviated Journal
Volume 566-567 Issue Pages 398-415
Keywords (down) Groundwater salinization, Coastal aquifer, Roussillon Basin, Isotopes, Westbay System, Barcarès and Canet sites
Abstract The Roussillon sedimentary Basin (South France) is a complex multi-layered aquifer, close to the Mediterranean Sea facing seasonally increases of water abstraction and salinization issues. We report geochemical and isotopic vertical variability in this aquifer using groundwater sampled with a Westbay System® at two coastal monitoring sites: Barcarès and Canet. The Westbay sampling allows pointing out and explaining the variation of water quality along vertical profiles, both in productive layers and in the less permeable ones where most of the chemical processes are susceptible to take place. The aquifer layers are not equally impacted by salinization, with electrical conductivity ranging from 460 to 43,000μS·cm−1. The δ2H–δ18O signatures show mixing between seawater and freshwater components with long water residence time as evidenced by the lack of contribution from modern water using 3H, 14C and CFCs/SF6. S(SO4) isotopes also evidence seawater contribution but some signatures can be related to oxidation of pyrite and/or organically bounded S. In the upper layers 87Sr/86Sr ratios are close to that of seawater and then increase with depth, reflecting water–rock interaction with argillaceous formations while punctual low values reflect interaction with carbonate. Boron isotopes highlight secondary processes such as adsorption/desorption onto clays in addition to mixings. At the Barcarès site (120m deep), the high salinity in some layers appear to be related neither to present day seawater intrusion, nor to Salses-Leucate lagoonwater intrusion. Groundwater chemical composition thus highlights binary mixing between fresh groundwater and inherited salty water together with cation exchange processes, water–rock interactions and, locally, sedimentary organic matter mineralisation probably enhanced by pyrite oxidation. Finally, combining the results of this study and those of Caballero and Ladouche (2015), we discuss the possible future evolution of this aquifer system under global change, as well as the potential management strategies needed to preserve quantitatively and qualitatively this water resource.
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ISSN 0048-9697 ISBN Medium
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Call Number THL @ christoph.kuells @ Peteletgiraud2016398 Serial 181
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Author Naranjo-Fernández, N.; Guardiola-Albert, C.; Montero-González, E.
Title Applying 3D geostatistical simulation to improve the groundwater management modelling of sedimentary aquifers: The case of Doñana (Southwest Spain) Type Journal Article
Year 2019 Publication Water Abbreviated Journal
Volume 11 Issue Pages 39
Keywords (down) geostatistics; hydrofacies; hydrogeological model; stochastic simulation; water balance
Abstract Mathematical groundwater modelling with homogeneous permeability zones has been used for decades to manage water resources in the Almonte-Marismas aquifer (southwest Spain). This is a highly heterogeneous detrital aquifer which supports valuable ecological systems in the Doñana National Park. The present study demonstrates that it is possible to better characterize this heterogeneity by numerical discretization of the geophysical and lithological data available. We identified six hydrofacies whose spatial characteristics were quantified with indicator variogram modelling. Sequential Indicator Simulation then made it possible to construct a 3D geological model. Finally, this detailed model was included in MODFLOW through the Model Muse interface. This final process is still a challenge due to the difficulty of downscaling to a handy numerical modelling scale. New piezometric surfaces and water budgets were obtained. The classical model with zones and the model with 3D simulation were compared to confirm that, for management purposes, the effort of improving the geological heterogeneities is worthwhile. This paper also highlights the relevance of including subsurface heterogeneities within a real groundwater management model in the present global change scenario.
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Call Number CUT @ phaedon.kyriakidis @ Fernandez2019 Serial 156
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Author Richter, B. C.; Kreidler, C.W.
Title Identification of Sources of Groundwater Salinization using Geochemical Techniques Type Journal Article
Year 1991 Publication EPA/600/2-91/064 Abbreviated Journal
Volume Issue Pages 259
Keywords (down) Geochemistry, USA, isotopes, salinization, ground water
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Corporate Author Bureau of Economic Geology, Univ. of Austin, Texas Thesis
Publisher EPA Place of Publication Editor Bledsoe, B.E.
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Call Number THL @ christoph.kuells @ Serial 187
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Author Bahir, M.; Ouhamdouch, S.; Carreira, P.M.
Title Isotopic and geochemical methods for studying water–rock interaction and recharge mode: application to the Cenomanian–Turonian and Plio-Quaternary aquifers of Essaouira Basin, Morocco Type Journal Article
Year 2018 Publication Mar. Freshwater Res. Abbreviated Journal
Volume 69 Issue 8 Pages 1290-1300
Keywords (down) geochemistry, semi-arid area, stable isotopes, water resources.
Abstract Study of the Cenomanian–Turonian and Plio–Quaternary aquifers of Essaouira basin (Western Morocco), based on the interpretation of geochemical (major elements) and isotopic (18O, 2H, 13C and 14C) data, has aided the understanding of the hydrodynamics of these aquifers, which is greatly affected by tectonics. Hydrochemical characteristics based on the bivariate diagrams of major ions (Cl–, SO42–, NO3–, HCO3–, Na+, Mg2+, K+ and Ca2+) and electrical conductivity and mineral saturation indices indicate that the origins of groundwater mineralisation are the result of: (1) evaporite dissolution; (2) cation exchange reactions; (3) and evaporation processes. Radiogenic isotopes (3H and 14C) have highlighted the presence of significant recent recharge in the eastern part of the basin, with groundwater moving according to the general flow path (south-east to north-west). Stable isotope data from the Essaouira basin plot along the Global Meteoric Water Line and below the Local Meteoric Water Line. This suggests that groundwater has been recharged under several different climate regimes.
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Call Number THL @ christoph.kuells @ Serial 191
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Author Jalali*, M.; Karami, S.; Marj, A.F.
Title On the problem of the spatial distribution delineation of the groundwater quality indicators via multivariate statistical and geostatistical approaches Type Journal Article
Year 2019 Publication Environ. Monit. Assess. Abbreviated Journal
Volume 191 Issue S2 Pages 323
Keywords (down) Factor analysis . Geostatistics .Hydrogeochemical parameters . Multivariate statistics .Simulation . Variogram
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Publisher Springer Science and Business Media LLC Place of Publication Editor
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Call Number CUT @ phaedon.kyriakidis @ Jalali2019 Serial 142
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