| Records |
| Author |
Daniele, L.; Vallejos, Á.; Corbella, M.; Molina, L.; Pulido-Bosch, A. |
| Title |
Hydrogeochemistry and geochemical simulations to assess water–rock interactions in complex carbonate aquifers: The case of Aguadulce (SE Spain) |
Type |
Journal Article |
| Year |
2013 |
Publication |
Applied Geochemistry |
Abbreviated Journal |
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| Volume |
29 |
Issue |
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Pages |
43-54 |
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| Abstract |
The hydrogeological unit of Aguadulce (Campo de Dalías aquifers, SE Spain) has a complex geometry. This fact, together with a continuous rise in water demand due to intensive agriculture and tourism create problems for groundwater quantity and quality. In this paper classic geochemical tools managed by means of GIS software and geochemical simulations are combined to delineate, identify and locate the possible physicochemical processes acting in the Aguadulce groundwater. Two main aquifers can be distinguished: the carbonate or lower aquifer of Triassic age, and the calcodetritic or upper aquifer of Plio-Quaternary age. Groundwaters from the latter are more saline and, assuming all chlorinity originates from seawater intrusion, the seawater contribution to their composition would be up to 7%. Nevertheless the carbonate aquifer appears not to be homogeneous: it is compartmentalised into 4 zones where different processes explain the different groundwaters compositions. Zone 4 samples (E margin of the carbonate aquifer) resemble those of the Plio-Quaternary aquifer, where calcite precipitation, dolomite and gypsum dissolution and some cation exchange (water–rock interaction) together with seawater–freshwater mixing occur. In contrast, water–rock interaction predominates in zones 1 and 3 of the carbonate aquifer. Moreover, zone 2 samples, located between zones 1 and 3, are explained by water–rock interaction in addition to mixing with Plio-Quaternary aquifer waters. The combination of geochemical simulations with GIS and hydrogeochemical analyses has proven to be effective in identifying and locating the different physicochemical processes in the aquifer areas, thus improving understanding of hydrogeochemistry in complex aquifers. |
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0883-2927 |
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THL @ christoph.kuells @ Daniele2013 |
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19 |
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| Author |
Edmunds, W.M. |
| Title |
Bromine geochemistry of british groundwaters |
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Journal Article |
| Year |
1996 |
Publication |
Mineralogical Magazine |
Abbreviated Journal |
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| Volume |
60 |
Issue |
399 |
Pages |
275-284 |
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\textlessp\textgreater The concentrations of Br in potable groundwaters in the United Kingdom range from 60 to 340 µg 1 \textlesssup\textgreater-1\textless/sup\textgreater . The occurrence of Br is described in terms of the Br/Cl weight ratio which enables small changes in bromide concentrations to be assessed in terms of salinity. Median values of Br/Cl in groundwaters range from 2.60 to 5.15 × 10 \textlesssup\textgreater−3\textless/sup\textgreater compared with a sea water ratio of 3.47× 10 \textlesssup\textgreater−3\textless/sup\textgreater . In recent shallow groundwaters the Br/Cl ratio is rather variable in response to a range of natural and anthropogenic inputs (marine and industrial aerosols, industrial and agricultural chemicals including road salt). Some slight enrichment in Br/Cl also occurs naturally during infiltration as a result of biogeochemical processes. \textless/p\textgreater |
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0026-461x |
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THL @ christoph.kuells @ Edmunds1996 |
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20 |
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El Yaouti, F.; El Mandour, A.; Khattach, D.; Benavente, J.; Kaufmann, O. |
| Title |
Salinization processes in the unconfined aquifer of Bou-Areg (NE Morocco): A geostatistical, geochemical, and tomographic study |
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Journal Article |
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2009 |
Publication |
Applied Geochemistry |
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24 |
Issue |
1 |
Pages |
16-31 |
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Hydrogeological and geochemical data, in conjunction with the results of an electrical imaging tomographic survey, were examined to determine the main factors and mechanisms controlling the groundwater chemistry and salinity of the unconfined aquifer of Bou-Areg, on the Mediterranean coast of NE Morocco. In addition, statistical and geochemical interpretation methods were used to identify the distribution of the salinity. Multivariate statistical analysis (cluster and principal component factors) revealed the main sources of contamination. Groups A, B, and C in the cluster analysis and Factors 1–3 (Factor 1: CE, Cl−, K+, SO42-, and Mg2+; Factor 2: Ca2+, HCO3-, and pH; Factor 3: NO3-) represent the ‘signature’ of seawater intrusion in the coastal zone, the influence of marly-gypsum outcrops in the upstream zone, and anthropogenic sources, respectively. The ionic delta, the ionic ratio, the saturation index, and Stuyfzand’s method were applied to evaluate geochemical processes. The results obtained indicate, on the one hand, the phenomenon of salinization in both the coastal and the upstream zones, and on the other, the dilution of groundwater by recharge. Cation exchange is shown to modify the concentration of ions in groundwater. Locally, with respect to salinization processes in the coastal zone, the results of electrical imaging tomography show that salinity increases both with depth and laterally inland from the coastline, due to seawater intrusion. |
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0883-2927 |
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THL @ christoph.kuells @ ElYaouti2009 |
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21 |
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Gat, J.R. |
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The relationship between surface and subsurface waters: water quality aspects in areas of low precipitation / Rapport entre les eaux de surface et les eaux souterraines: aspects des propriétés caractéristiques de l’eau dans les zones à précipitation faible |
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Journal Article |
| Year |
1980 |
Publication |
Hydrological Sciences Bulletin |
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| Volume |
25 |
Issue |
3 |
Pages |
257-267 |
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In the temperate and semiarid environment the salinity of both surface and subsurface(meteoric) waters is dominated by the weathering products of soil and aquifer minerals, since even surface waters have a history of subsurface flow. In the desert environment, in contrast, surface flows are more superficial and their chemistry dominated by the aeolian salinity. This has both a marine input and
a contribution from recycled salinity from surface accumulation of evaporitic minerals. Both these sources have chloride (and to a lesser extent sulphate) as the dominant anion. |
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0303-6936 |
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THL @ christoph.kuells @ Gat1980 |
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22 |
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| Author |
Bobba, A.G. |
| Title |
Mathematical models for saltwater intrusion in coastal aquifers |
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Journal Article |
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1993 |
Publication |
Water Resources Management |
Abbreviated Journal |
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7 |
Issue |
1 |
Pages |
3-37 |
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Flow of freshwater and saltwater intrusion in coastal aquifers has drawn the attention of many investigators. Several laboratory, as well as mathematical models have been developed to study the pattern of flow of groundwater in coastal aquifers. Mathematical models have wider range of application and are the concern of this paper. Due to the complex nature of the problem, each of these mathematical models are based on certain simplifying assumptions and approximations. This paper presents a critical review of various methods of solution which have been proposed. The validity of the results abtained and the limitations of these models are also discussed. |
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Edition |
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1573-1650 |
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THL @ christoph.kuells @ Bobba.1993 |
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14 |
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