Russak, A., Sivan, O., & Yechieli, Y. (2016). Trace elements (Li, B, Mn and Ba) as sensitive indicators for salinization and freshening events in coastal aquifers. Chemical Geology, 441, 35–46.
Abstract: The current global intrusion of seawater into coastal aquifers causes salinization of groundwater and thus significant degradation of its quality. This study quantified the effect of seawater intrusion and freshening events in coastal aquifers on trace elements (Li, B, Mn and Ba) across the fresh-saline water interface (FSI) and their possible use as indicators for these events. This was done by combining field data and column experiments simulating these events. The experiments enabled quantification of the processes affecting the trace element composition and examination of whether salinization and freshening events are geochemically reversible, which has been seldom investigated. The dominant process affecting trace element composition during salinization and freshening is ion exchange. The results of the experiments show that the concentrations of major cations and Li+ were reversible during salinization and freshening, whereas B, Mn2+ and Ba2+ were not. During salinization, Li+ and B were depleted due to sorption by 10 and 100μmol·L−1, respectively, to about half of their expected conservative concentrations. The relative depletion of Li+ increased with distance from the shore, representing the propagation of salinization. Ba2+ and Mn2+ were desorbed from the sediment during salinization and enriched by tenfold in the aqueous phase compared to their concentration in seawater ( 0.1 μeq·L−1). During freshening both were depleted by almost tenfold compared to their concentration in fresh groundwater ( 0.7 μeq·L−1). The depletion of Mn2+ is a sensitive marker for freshening because Mn2+ has a strong affinity to the solid phase. Moreover, this study shows that both Mn2+ and Ba2+ can be used as sensitive hydrogeochemical tools to distinguish between salinization and freshening events in the FSI zone in coastal aquifers.
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Siarkos, I., & Latinopoulos, P. (2016). Modeling seawater intrusion in overexploited aquifers in the absence of sufficient data: application to the aquifer of Nea Moudania, northern Greece. Hydrogeology J., 24, 2123–2141.
Abstract: In many coastal areas, overexploitation of groundwater resources has led both to the quantitative degradation of local aquifers and the deterioration of groundwater quality due to seawater intrusion. To investigate the behavior of coastal aquifers under these conditions, numerical modeling is usually implemented; however, the proper implementation of numerical models requires a large amount of data, which are often not available due to the time-consuming and costly process of obtaining them. In the present study, the investigation of the behavior of coastal aquifers under the lack of adequate data is
attempted by developing a methodological framework consisting of a series of numerical simulations: a steady-state, a false-transient and a transient simulation. The sequence and the connection between these simulations constitute the backbone of the whole procedure aimed at adjusting the various
model parameters, as well as obtaining the initial conditions for the transient simulation. The validity of the proposed methodology is tested through evaluation of the model calibration procedure and the estimation of the simulation errors (mean error, mean absolute error, root mean square error, mean relative error) using the case of Nea Moudania basin, northern Greece. Furthermore, a sensitivity analysis is performed in order to minimize the error estimates and thus to maximize the reliability of the models. The results of the whole procedure affirm the proper implementation of the developed methodology under specific conditions and assumptions due to the lack of sufficient data, while they give a clear picture of the aquifer’s quantitative and qualitative status.
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Satrio, S., Prasetio, R., Hadian, M., Syafri, I. (2016). Stable Isotopes and Hydrochemistry Approach for Determining the Salinization Pattern of Shallow Groundwater in Alluvium Deposit Semarang, Central Java. Indonesian Journal on Geoscience, 4.
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Greene, R., Timms, W., Rengasamy, P., Arshad, M., & Cresswell, R. (2016). Soil and Aquifer Salinization: Toward an Integrated Approach for Salinity Management of Groundwater. In A. J. Jakeman, O. Barreteau, R. J. Hunt, J. - D. Rinaudo, & A. Ross (Eds.), Integrated Groundwater Management: Concepts, Approaches and Challenges (pp. 377–412). Cham: Springer International Publishing.
Abstract: Degradation of the quality of groundwater due to salinization processes is one of the key issues limiting the global dependence on groundwater in aquifers. As the salinization of shallow aquifers is closely related to root-zone salinization, the two must be considered together. This chapter initially describes the physical and chemical processes causing salinization of the root-zone and shallow aquifers, highlighting the dynamics of these processes and how they can be influenced by irrigation and drainage practices, thus illustrating the connectivity between soil and groundwater salinization. The processes leading to aquifer salinization in both inland and coastal areas are discussed. The roles of extractive resource industries, such as mining and coal bed methane operations, in causing aquifer salinization are also outlined. Hydrogeochemical changes occurring during salinization of aquifers are examined with the aid of Piper and Mixing Diagrams. The chapter then illustrates the extent of the problem of groundwater salinization as influenced by management and policy using two case studies. The first is representative of a developing country and explores management of salt-affected soils in the Indus Valley, Pakistan, while the second looks at a developed country, and illustrates how through monitoring we can deduce causes of shallow aquifer salinity in the Namoi Catchment of NSW, Australia. Finally, there is a section on integration and conclusions where we illustrate how management to mitigate salinization needs to be integrated with policy to diminish the threat to productivity that occurs with groundwater degradation.
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Llopis-Albert, C., Merigó, J. M., & Xu, Y. (2016). A coupled stochastic inverse/sharp interface seawater intrusion approach for coastal aquifers under groundwater parameter uncertainty. Journal of Hydrology, 540, 774–783.
Abstract: This paper presents an alternative approach to deal with seawater intrusion problems, that overcomes some of the limitations of previous works, by coupling the well-known SWI2 package for MODFLOW with a stochastic inverse model named GC method. On the one hand, the SWI2 allows a vertically integrated variable-density groundwater flow and seawater intrusion in coastal multi-aquifer systems, and a reduction in number of required model cells and the elimination of the need to solve the advective-dispersive transport equation, which leads to substantial model run-time savings. On the other hand, the GC method allows dealing with groundwater parameter uncertainty by constraining stochastic simulations to flow and mass transport data (i.e., hydraulic conductivity, freshwater heads, saltwater concentrations and travel times) and also to secondary information obtained from expert judgment or geophysical surveys, thus reducing uncertainty and increasing reliability in meeting the environmental standards. The methodology has been successfully applied to a transient movement of the freshwater-seawater interface in response to changing freshwater inflow in a two-aquifer coastal aquifer system, where an uncertainty assessment has been carried out by means of Monte Carlo simulation techniques. The approach also allows partially overcoming the neglected diffusion and dispersion processes after the conditioning process since the uncertainty is reduced and results are closer to available data.
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