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Author Araguás-Araguás, L. openurl 
  Title Identification of the mechanisms and origin of salinization of groundwater in coastal aquifers by isotope techniques Type Journal Article
  Year 2003 Publication (down) Tecnología de la intrusión de agua de mar en acuíferos costeros, Países Mediterráneos Abbreviated Journal  
  Volume Issue Pages 365-371  
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  Abstract When assessing the origin of salinity and the mechanisms of salinization in coastal aquifers, hydrogeologists may consider the combined use of certain geochemical tools to assess critical aspects of the hydrogeological setting of the system. These tools are based in the integrated use of chemical (major ions, trace elements and ionic ratios) and isotope parameters (oxygen, hydrogen, sulphur, carbon, strontium and boron). The problem of groundwater salinization in coastal aquifers, besides active seawater intrusion, may be affected by several human activities that accelerate the progressive deterioration of water quality, such as concentrated pumping, intensive agricultural practices including return flows or reuse of waste waters from urban or industrial origin. The characterisation of the perating processes and mechanisms of salinization is a requisite for a proper management of groundwater resources and for adopting remediation strategies. In this contribution the potential role of several isotopic tools in these studies is briefly described.  
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  Call Number THL @ christoph.kuells @ article Serial 86  
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Author Elrashidi, M.A.; Adriano, D.C.; Workman, S.M.; Lindsay, W.L. openurl 
  Title Chemical equilibria of selenium in soils: a theoretical development1 Type Journal Article
  Year 1987 Publication (down) Soil Science Abbreviated Journal  
  Volume 144 Issue 2 Pages 141-152  
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  Publisher Lww Place of Publication Editor  
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  Call Number THL @ luqianxue.zhang @ elrashidi1987chemical Serial 103  
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Author Cary, L.; Petelet-Giraud, E.; Bertrand, G.; Kloppmann, W.; Aquilina, L.; Martins, V.; Hirata, R.; Montenegro, S.M.G.L.; Pauwels, H.; Chatton, E.; Franzen, Melissa; Aurouet, A.; Lasseur, E.; Picot-Colbeaux, G.; Guerrot, C.; Fléhoc, C.; Labasque, T.; Santos, Jeane Glaucia; Paiva, Anderson L.R.; Braibant, G.; Pierre, D. url  doi
openurl 
  Title Origins and processes of groundwater salinization in the urban coastal aquifers of Recife (Pernambuco, Brazil): a multi-isotope approach Type Journal Article
  Year 2015 Publication (down) Science of the Total Environment Abbreviated Journal  
  Volume 530-531 Issue Pages 411-429  
  Keywords Salinization origins; Salinization processes; Groundwater; Coastal aquifer; Strontium isotopes; Boron isotopes; Recife; Brazil  
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  Corporate Author Thesis  
  Publisher Elsevier Place of Publication Editor  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ cary:hal-01161949 Serial 85  
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Author Faye, S.; Maloszewski, P.; Stichler, W.; Trimborn, P.; Faye, S. C.; Gaye, C. url  openurl
  Title Groundwater salinization in the Saloum (Senegal) delta aquifer: minor elements and isotopic indicators Type Journal Article
  Year 2005 Publication (down) Science of The Total Environment Abbreviated Journal  
  Volume 343 Issue 1 Pages 243-259  
  Keywords Minor elements, Hydrochemistry, Sorption/desorption, Mixing model, Salinization  
  Abstract The hydrochemistry of minor elements bromide (Br), boron (B), strontium (Sr), environmental stable isotopes (18O and 2H) together with major-ion chemistry (chloride, sodium, calcium) has been used to constrain the source(s), relative age, and processes of salinization in the Continental Terminal (CT) aquifer in the Saloum (mid-west Senegal) region. Seventy-one groundwater wells which include 24 wells contaminated by saltwater and three sites along the hypersaline Saloum River were sampled to obtain additional information on the hydrochemical characteristics of the groundwater defined in previous studies. Use of Br against Cl confirms the Saloum River saline water intrusion up to a contribution of 7% into the aquifer. In addition to this recent intrusion, a relatively ancient intrusion of the Saloum River water which had reached at least as far as 20 km south from the source was evidenced. The high molar ratio values of Sr/Cl and Sr/Ca indicate an additional input of strontium presumably derived from carbonate precipitation/dissolution reactions and also via adsorption reactions. The variable B concentrations (7–650 μg/L) found in the groundwater samples were tested against the binary mixing model to evaluate the processes of salinization which are responsible for the investigated system. Sorption of B and depletion of Na occur as the Saloum river water intrudes the aquifer (salinization) in the northern part of the region, whereas B desorption and Na enrichment occur as the fresh groundwater flushing displaces the saline waters in the coastal strip (refreshening). In the central zone where ancient intrusion prevailed, the process of freshening of the saline groundwater is indicated by the changes in major-ion chemistry as well as B desorption and Na enrichment. In addition to these processes, stable isotopes reveal that mixing with recently infiltrating waters and evaporation contribute to the changes in isotopic signature.  
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  Call Number THL @ christoph.kuells @ Faye2005243 Serial 173  
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Author Petelet-Giraud, E.; Négrel, P.; Aunay, B.; Ladouche, B.; Bailly-Comte, V.; Guerrot, C.; Flehoc, C.; Pezard, P.; Lofi, J.; Dörfliger, N. url  doi
openurl 
  Title Coastal groundwater salinization: Focus on the vertical variability in a multi-layered aquifer through a multi-isotope fingerprinting (Roussillon Basin, France) Type Journal Article
  Year 2016 Publication (down) Science of The Total Environment Abbreviated Journal  
  Volume 566-567 Issue Pages 398-415  
  Keywords Groundwater salinization, Coastal aquifer, Roussillon Basin, Isotopes, Westbay System, Barcarès and Canet sites  
  Abstract The Roussillon sedimentary Basin (South France) is a complex multi-layered aquifer, close to the Mediterranean Sea facing seasonally increases of water abstraction and salinization issues. We report geochemical and isotopic vertical variability in this aquifer using groundwater sampled with a Westbay System® at two coastal monitoring sites: Barcarès and Canet. The Westbay sampling allows pointing out and explaining the variation of water quality along vertical profiles, both in productive layers and in the less permeable ones where most of the chemical processes are susceptible to take place. The aquifer layers are not equally impacted by salinization, with electrical conductivity ranging from 460 to 43,000μS·cm−1. The δ2H–δ18O signatures show mixing between seawater and freshwater components with long water residence time as evidenced by the lack of contribution from modern water using 3H, 14C and CFCs/SF6. S(SO4) isotopes also evidence seawater contribution but some signatures can be related to oxidation of pyrite and/or organically bounded S. In the upper layers 87Sr/86Sr ratios are close to that of seawater and then increase with depth, reflecting water–rock interaction with argillaceous formations while punctual low values reflect interaction with carbonate. Boron isotopes highlight secondary processes such as adsorption/desorption onto clays in addition to mixings. At the Barcarès site (120m deep), the high salinity in some layers appear to be related neither to present day seawater intrusion, nor to Salses-Leucate lagoonwater intrusion. Groundwater chemical composition thus highlights binary mixing between fresh groundwater and inherited salty water together with cation exchange processes, water–rock interactions and, locally, sedimentary organic matter mineralisation probably enhanced by pyrite oxidation. Finally, combining the results of this study and those of Caballero and Ladouche (2015), we discuss the possible future evolution of this aquifer system under global change, as well as the potential management strategies needed to preserve quantitatively and qualitatively this water resource.  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Peteletgiraud2016398 Serial 181  
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