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Neal, C., Neal, M., Hughes, S., Wickham, H., Hill, L., & Harman, S. (2007). Bromine and bromide in rainfall, cloud, stream and groundwater in the Plynlimon area of mid-Wales. Hydrology and Earth System Sciences, 11(1), 301–312.
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Park, H., & Schlesinger, W. (2002). Global biochemical cycle of boron. Global Biogeochemical Cycles, 16, 1072.
Abstract: The global Boron (B) cycle is primarily driven by a large flux (1.44 Tg B/yr) through the atmosphere derived from seasalt aerosols. Other significant sources of atmospheric boron include emissions during the combustion of biomass (0.26-0.43 Tg B/yr) and coal, which adds 0.20 Tg B/yr as an anthropogenic contribution. These known inputs to the atmosphere cannot account for the boron removed from the atmosphere during rainfall (3.0 Tg B/yr) and estimated dry deposition (1.3-2.7 Tg B/yr). In addition to atmospheric deposition, rock weathering is a source of boron (0.19 Tg B/yr) for terrestrial ecosystems, and humans mine about 0.31 Tg B/yr from the Earth's crust. More than 4.8 Tg B/yr circulates in the biogeochemical cycle of land plants, and about 0.53-0.63 Tg B/yr is carried from land to sea by rivers. The biogeochemical cycle of boron in the sea includes 4.4 Tg B/yr circulating in the marine biosphere, and an annual loss of 0.47 Tg B/yr to the oceanic crust via a variety of sedimentary processes that collectively remove only a small fraction of the total annual inputs to the oceans. Thus with our current understanding of the global biogeochemistry of B, the atmospheric budget shows outputs > inputs, while the marine compartments show inputs > outputs. Despite these uncertainties, it is clear that the human perturbation of the global B cycle has more than doubled the mobilization of B from the crust and contributes significantly to the B transport in rivers.
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Bahir, M., Ouhamdouch, S., & Carreira, P. M. (2018). Geochemical and isotopic approach to decrypt the groundwater salinization origin of coastal aquifers from semi-arid areas (Essaouira basin, Western Morocco). Environmental Earth Sciences, 77(13), 485.
Abstract: In arid and semi-arid areas, the groundwater is the main source of water supply and agricultural activity. Overexploitation of coastal aquifers and pollution vulnerability are among the main problems related to groundwater resources assessment and management in these zones. In fact, in the last decades, these resources have been threatened by a degradation of their quality and quantity that furthers natural and anthropic effects, such as climate change, seawater intrusion and overexploitation. However, the protection and management of these resources requires knowledge of the origin of their mineralization. In this study, the Essaouira basin is selected as a typical example. Stable isotopes (18O and 2H) together with geochemical data were used to identify the groundwater salinization origin in the coastal aquifers of the Essaouira basin. The results of both the approaches show that the groundwater mineralization is due to: (1) the dissolution of salt minerals, (2) the ion exchange phenomena, (3) seawater intrusion, and (4) sulphate reduction. Also, the recharge is supported by fast infiltration of oceanic precipitation without significant evaporation.
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Merkel, B., Planer-Friedrich, B., & Nordstrom, D. (2008). Groundwater Geochemistry: A Practical Guide to Modeling of Natural and Contaminated Aquatic Systems. Groundwater Geochemistry, by B.J. Merkel and B. Planer-Friedrich. Edited by D.K. Nordstrom. Berlin: Springer, 2008. ISBN: 978-3-540-74667-6, .
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Mahindawansha, A., Külls, C., Kraft, P., & Breuer, L. (2019). Estimating water flux and evaporation losses using stable isotopes of soil water from irrigated agricultural crops in tropical humid regions. Hydrology and Earth System Sciences Discussions, 2019, 1–28.
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