Records |
Author |
Han, D.M.; Song, X.F.; Currell, M.J.; Yang, J.L.; Xiao, G.Q. |
Title |
Chemical and isotopic constraints on evolution of groundwater salinization in the coastal plain aquifer of Laizhou Bay, China |
Type |
Journal Article |
Year |
2014 |
Publication |
Journal of Hydrology |
Abbreviated Journal |
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Volume |
508 |
Issue |
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Pages |
12-27 |
Keywords |
Laizhou Bay, Coastal aquifers, Groundwater hydrochemistry, Stable isotopes, Saltwater intrusion |
Abstract |
Summary A hydrochemical-isotopic investigation of the Laizhou Bay Quaternary aquifer in north China provides new insights into the hydrodynamic and geochemical relationships between freshwater, seawater and brine at different depths in coastal sediments. Saltwater intrusion mainly occurs due to two cones of depression caused by concentrated exploitation of fresh groundwater in the south, and brine water for salt production in the north. Groundwater is characterized by hydrochemical zonation of water types (ranging from Ca–HCO3 to Na–Cl) from south to north, controlled by migration and mixing of saline water bodies with the regional groundwater. The strong adherence of the majority of ion/Cl ratios to mixing lines between freshwater and saline water end-members (brine or seawater) indicates the importance of mixing under natural and/or anthropogenic influences. Examination of the groundwater stable isotope δ18O and δ2H values (between −9.5‰ and −3.0‰ and −75‰ and −40‰, respectively) and chloride contents (∼2 to 1000meq/L) of the groundwater indicate that the saline end-member is brine rather than seawater, and most groundwater samples plot on mixing trajectories between fresh groundwater (δ18O of between −6.0‰ and −9.0‰; Cl<5meq/L) and sampled brines (δ18O of approximately −3.0‰ and Cl>1000meq/L). Locally elevated Na/Cl ratios likely result from ion exchange in areas of long-term freshening. The brines, with radiocarbon activities of ∼30 to 60 pMC likely formed during the Holocene as a result of the sequence of transgression-regression and evaporation; while deep, fresh groundwater with depleted stable isotopic values (δ18O=−9.7‰ and δ2H=−71‰) and low radiocarbon activity (<20 pMC) was probably recharged during a cooler period in the late Pleistocene, as is common throughout northern China. An increase in the salinity and tritium concentration in some shallow groundwater sampled in the 1990s and re-sampled here indicates that intensive brine extraction has locally resulted in rapid mixing of young, fresh groundwater and saline brine. The δ18O and δ2H values of brines (∼−3.0‰ and −35‰) are much lower than that of modern seawater, which could be explained by 1) mixing of original (δ18O enriched) brine that was more saline than presently observed, with fresh groundwater recharged by precipitation and/or 2) dilution of the palaeo-seawater with continental runoff prior to and/or during brine formation. The first mechanism is supported by relatively high Br/Cl molar ratios (1.7×10−3–2.5×10−3) in brine water compared with ∼1.5×10−3 in seawater, which could indicate that the brines originally reached halite saturation and were subsequently diluted with fresher groundwater over the long-term. Decreasing 14C activities with increasing sampling depth and increasing proximity to the coastline indicate that the south coastal aquifer in Laizhou Bay is dominated by regional lateral flow, on millennial timescales. |
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0022-1694 |
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THL @ christoph.kuells @ Han201412 |
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174 |
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Hammami Abidi, J.; Farhat, B.; Ben Mammou, A.; Oueslati, N. |
Title |
Characterization of Recharge Mechanisms and Sources of Groundwater Salinization in Ras Jbel Coastal Aquifer (Northeast Tunisia) Using Hydrogeochemical Tools, Environmental Isotopes, GIS, and Statistics |
Type |
Journal Article |
Year |
2017 |
Publication |
Journal of Chemistry |
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Volume |
2017 |
Issue |
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Pages |
8610894 |
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Abstract |
Groundwater is among the most available water resources in Tunisia; it is a vital natural resource in arid and semiarid regions. Located in north-eastern Tunisia, the Metline-Ras Jbel-Raf Raf aquifer is a mio-plio-quaternary shallow coastal aquifer, where groundwater is the most important source of water supply. The major ion hydrochemistry and environmental isotope composition δ18O, δ2H were investigated to identify the recharge sources and processes that affect the groundwater salinization. The combination of hydrogeochemical, isotopic, statistical, and GIS approaches demonstrates that the salinity and the groundwater composition are largely controlled by the water-rock interaction particularly the dissolution of evaporate minerals and the ion exchange process, the return flow of the irrigation water, agricultural fertilizers, and finally saltwater intrusion which started before 1980 and which is partially mitigated by the artificial recharge since 1993. As for the stable isotope signatures, results showed that groundwater samples lay on and around the local meteoric water line LMWL; hence, this arrangement signifies that the recharge of the Ras Jbel aquifer is ensured by recent recharge from Mediterranean air masses. |
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Hindawi KW |
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2090-9063 |
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THL @ christoph.kuells @ |
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189 |
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Bouzourra, H.; Bouhlila, R.; Elango, L.; Slama, F.; Ouslati, N. |
Title |
Characterization of mechanisms and processes of groundwater salinization in irrigated coastal area using statistics, GIS, and hydrogeochemical investigations |
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Journal Article |
Year |
2015 |
Publication |
Environmental Science and Pollution Research |
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22 |
Issue |
4 |
Pages |
2643-2660 |
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Springer |
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THL @ luqianxue.zhang @ bouzourra2015characterization |
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78 |
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Pearce, C.R.; Parkinson, I.J.; Gaillardet, J.; Chetelat, B.; Burton, K.W. |
Title |
Characterising the stable (δ88/86Sr) and radiogenic (87Sr/86Sr) isotopic composition of strontium in rainwater |
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Journal Article |
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2015 |
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Chemical Geology |
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409 |
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54-60 |
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Elsevier |
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THL @ luqianxue.zhang @ pearce2015characterising |
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96 |
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Author |
Edmunds, W.M. |
Title |
Bromine geochemistry of british groundwaters |
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Journal Article |
Year |
1996 |
Publication |
Mineralogical Magazine |
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60 |
Issue |
399 |
Pages |
275-284 |
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\textlessp\textgreater The concentrations of Br in potable groundwaters in the United Kingdom range from 60 to 340 µg 1 \textlesssup\textgreater-1\textless/sup\textgreater . The occurrence of Br is described in terms of the Br/Cl weight ratio which enables small changes in bromide concentrations to be assessed in terms of salinity. Median values of Br/Cl in groundwaters range from 2.60 to 5.15 × 10 \textlesssup\textgreater−3\textless/sup\textgreater compared with a sea water ratio of 3.47× 10 \textlesssup\textgreater−3\textless/sup\textgreater . In recent shallow groundwaters the Br/Cl ratio is rather variable in response to a range of natural and anthropogenic inputs (marine and industrial aerosols, industrial and agricultural chemicals including road salt). Some slight enrichment in Br/Cl also occurs naturally during infiltration as a result of biogeochemical processes. \textless/p\textgreater |
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0026-461x |
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THL @ christoph.kuells @ Edmunds1996 |
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20 |
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