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Moral, F.; Cruz-Sanjulián, J.J.; Olías, M. |
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Title |
Geochemical evolution of groundwater in the carbonate aquifers of Sierra de Segura (Betic Cordillera, southern Spain) |
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Journal Article |
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Year |
2008 |
Publication |
Journal of Hydrology |
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360 |
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1 |
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281-296 |
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Sierra de Segura (Betic Cordillera), with a total area of over 3000km2, is the source of the two principal rivers in southern Spain, the Guadalquivir and the Segura. Due to the orographic effect of these mountains, precipitations are considerably more abundant than in nearby lowland areas, where the climate is semi-arid. Sierra de Segura is constituted of Mesozoic and Cenozoic sedimentary rocks, among which there are thick limestone–dolomitic formations which have given rise to extensive outcrops of permeable materials. In geomorphological terms, there is a large plateau intensively karstified that constitutes the main recharge area. Discharge takes place via a large number of springs, of which the 50 most important add up to a mean spring flow of about 13,500l/s. The active geochemical processes in aquifers of Sierra de Segura, with their corresponding time sequence, are: dissolution of CO2, dissolution of calcite, incongruent dissolution of dolomite, dedolomitization, exsolution of CO2, and precipitation of calcite. More evolved water has higher temperature, magnesium content and Mg/Ca ratio; therefore, these parameters can be utilised as indicators of the degree of hydrochemical evolution. In addition, a good correlation between water temperature and magnesium concentration (or Mg/Ca ratio) indicates that an increase in temperature accelerates the kinetics of the dissolution of dolomite. Finally, the distribution of the temperatures in the vadose zone, determined by atmospheric thermal gradient, implies an apparent stratification of the predominant hydrochemical processes and of the groundwater physical and chemical characteristics. |
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0022-1694 |
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THL @ christoph.kuells @ Moral2008 |
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32 |
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Bouchaou, L.; Michelot, J.L.; Vengosh, A.; Hsissou, Y.; Qurtobi, M.; Gaye, C.B.; Bullen, T.D.; Zuppi, G.M. |
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Application of multiple isotopic and geochemical tracers for investigation of recharge, salinization, and residence time of water in the Souss–Massa aquifer, southwest of Morocco |
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Journal Article |
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2008 |
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Journal of Hydrology |
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352 |
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3 |
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267-287 |
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Groundwater and surface water in Souss–Massa basin in the west-southern part of Morocco is characterized by a large variation in salinity, up to levels of 37gL−1. The high salinity coupled with groundwater level decline pose serious problems for current irrigation and domestic water supplies as well as future exploitation. A combined hydrogeologic and isotopic investigation using several chemical and isotopic tracers such as Br/Cl, δ18O, δ2H, 3H, 87Sr/86Sr, δ11B, and 14C was carried out in order to determine the sources of water recharge to the aquifer, the origin of salinity, and the residence time of water. Stable isotope, 3H and 14C data indicate that the high Atlas mountains in the northern margin of the Souss–Massa basin with high rainfall and low δ18O and δ2H values (−6 to −8‰ and −36 to −50‰) is currently constitute the major source of recharge to the Souss–Massa shallow aquifer, particularly along the eastern part of the basin. Localized stable isotope enrichments offset meteoric isotopic signature and are associated with high nitrate concentrations, which infer water recycling via water agricultural return flows. The 3H and 14C data suggest that the residence time of water in the western part of the basin is in the order of several thousands of years; hence old water is mined, particularly in the coastal areas. The multiple isotope analyses and chemical tracing of groundwater from the basin reveal that seawater intrusion is just one of multiple salinity sources that affect the quality of groundwater in the Souss–Massa aquifer. We differentiate between modern seawater intrusion, salinization by remnants of seawater entrapped in the middle Souss plains, recharge of nitrate-rich agricultural return flow, and dissolution of evaporate rocks (gypsum and halite minerals) along the outcrops of the high Atlas mountains. The data generated in this study provide the framework for a comprehensive management plan in which water exploitation should shift toward the eastern part of the basin where current recharge occurs with young and high quality groundwater. In contrast, we argued that the heavily exploited aquifer along the coastal areas is more vulnerable given the relatively longer residence time of the water and salinization processes in this part of the aquifer. |
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0022-1694 |
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THL @ christoph.kuells @ Bouchaou2008 |
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17 |
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Kafri, U.; Goldman, M.; Lyakhovsky, V.; Scholl, C.; Helwig, S.; Tezkan, B. |
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The configuration of the fresh–saline groundwater interface within the regional Judea Group carbonate aquifer in northern Israel between the Mediterranean and the Dead Sea base levels as delineated by deep geoelectromagnetic soundings |
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Journal Article |
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2007 |
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Journal of Hydrology |
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344 |
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1 |
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123-134 |
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A combined high resolution short offset transient electromagnetic (SHOTEM) and deep sounding, long offset (LOTEM) survey has been carried out along two traverses between the Mediterranean Sea and the Jordan-Dead Sea Rift (DSR). The DSR is located in the study area some 200–250m below sea level. The measurements detected a deep conductor, the top of which exhibited a regular behavior along the both traverses, declining from the Mediterranean to the DSR base level. The geometry of this geoelectric boundary coincides fairly well with the configuration of a supposed fresh/saline groundwater interface as also obtained by both numerical and physical modeling for the known hydrogeological conditions in the study area. Therefore the detected geoelectric boundary is identified with the interface, supporting the hypothesis of current seawater intrusion into the deep regional aquifers between the Mediterranean and the DSR base levels. The intrusion causes the salination of fresh groundwater within the aquifers as well as the salination of the Sea of Galilee. |
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0022-1694 |
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THL @ christoph.kuells @ Kafri2007 |
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27 |
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Faye, S.; Maloszewski, P.; Stichler, W.; Trimborn, P.; Faye, S. C.; Gaye, C. |
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Groundwater salinization in the Saloum (Senegal) delta aquifer: minor elements and isotopic indicators |
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Journal Article |
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2005 |
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Science of The Total Environment |
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343 |
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1 |
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243-259 |
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Minor elements, Hydrochemistry, Sorption/desorption, Mixing model, Salinization |
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The hydrochemistry of minor elements bromide (Br), boron (B), strontium (Sr), environmental stable isotopes (18O and 2H) together with major-ion chemistry (chloride, sodium, calcium) has been used to constrain the source(s), relative age, and processes of salinization in the Continental Terminal (CT) aquifer in the Saloum (mid-west Senegal) region. Seventy-one groundwater wells which include 24 wells contaminated by saltwater and three sites along the hypersaline Saloum River were sampled to obtain additional information on the hydrochemical characteristics of the groundwater defined in previous studies. Use of Br against Cl confirms the Saloum River saline water intrusion up to a contribution of 7% into the aquifer. In addition to this recent intrusion, a relatively ancient intrusion of the Saloum River water which had reached at least as far as 20 km south from the source was evidenced. The high molar ratio values of Sr/Cl and Sr/Ca indicate an additional input of strontium presumably derived from carbonate precipitation/dissolution reactions and also via adsorption reactions. The variable B concentrations (7–650 μg/L) found in the groundwater samples were tested against the binary mixing model to evaluate the processes of salinization which are responsible for the investigated system. Sorption of B and depletion of Na occur as the Saloum river water intrudes the aquifer (salinization) in the northern part of the region, whereas B desorption and Na enrichment occur as the fresh groundwater flushing displaces the saline waters in the coastal strip (refreshening). In the central zone where ancient intrusion prevailed, the process of freshening of the saline groundwater is indicated by the changes in major-ion chemistry as well as B desorption and Na enrichment. In addition to these processes, stable isotopes reveal that mixing with recently infiltrating waters and evaporation contribute to the changes in isotopic signature. |
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0048-9697 |
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THL @ christoph.kuells @ Faye2005243 |
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173 |
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Pulido-Leboeuf, P.; Pulido-Bosch, A.; Calvache, M.L.; Vallejos, Á.; Andreu, J.M. |
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Strontium, SO42-/Cl- and Mg2+/Ca2+ ratios as tracers for the evolution of seawater into coastal aquifers: the example of Castell de Ferro aquifer (SE Spain) |
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2003 |
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Comptes Rendus Geoscience |
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335 |
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14 |
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1039-1048 |
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Elsevier |
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THL @ luqianxue.zhang @ pulido2003strontium |
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71 |
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