@Article{Hanshaw+Back1985, author="Hanshaw, B. B. and Back, W.", title="Deciphering hydrological systems by means of geochemical processes", journal="Hydrological Sciences Journal", year="1985", volume="30", number="2", pages="257--271", abstract="The distribution of permeability and chemical character of groundwater in carbonate aquifers is significantly influenced by the many diagenetic processesand reactions that occur in the early development of these rocks. Many of these diagenetic processes occur in the transition zone formed as the carbonate sediments emerge from the marine environment and become fresh-water aquifers. Analyses of trace elements and isotopesindicate that calcite cements and dolomites are formed in this groundwater mixing zone. Reverse reactions such as mineral dissolution and dedolomitization occur in carbonate aquifer systems. The geochemical reactivity of the fresh-water/salt-water mixing zone results from the nonlinearity of geochemical parameters as a function of ionic strength and causes extensive dissolution in coastal carbonate rocks. Interpretation of geochemical reactions and isotopic composition of groundwater provides a method to determine hydrological parameterssuch as porosity, hydraulic conductivity, and groundwater flow rates. This geochemical method is largely independent of the more conventional approach of determining these parameters by an evaluation of physical properties of aquifer systems.", optnote="exported from refbase (http://www.uhydro.de/refbase/show.php?record=25), last updated on Wed, 18 Mar 2020 14:53:36 +0100", issn="0262-6667", doi="10.1080/02626668509490988", opturl="http://www.tandfonline.com/doi/abs/10.1080/02626668509490988" }